Potentially, yes.
Employment income and freelance/self-employed income are treated separately for tax purposes. If your additional income means you need to complete a Self Assessment return, your salary, tax already deducted through PAYE and your self-employed income and allowable expenses would normally all need to be considered.
Keep records of:
freelance invoices; payments received; business expenses; equipment purchases; software subscriptions; relevant travel; other costs directly connected with the freelance activity.
Do not wait until the filing deadline to organise everything. Keeping the records properly from the beginning makes the return considerably easier.